Potassium N-bromo-4-chloro-2-methylbenzenesulfonamidate monohydrate
نویسندگان
چکیده
In the title compound, K(+)·C7H6BrClNO2S(-)·H2O, the K(+) cation is hepta-coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl-benzene-sulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O-H⋯Br and O-H⋯N hydrogen bonds.
منابع مشابه
Potassium N-bromo-2-methylbenzenesulfonamidate sesquihydrate
In the structure of the title compound, K(+)·C(7)H(7)BrNO(2)S(-)·1.5H(2)O, the K(+) ion is hepta-coordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-bromo-2-methyl-benzene-sulfonamide anions. The S-N distance of 1.577 (5) Å is consistent with an S=N double bond. The crystal structure comprises sheets in the ac plane which are further stabilized by O-H⋯Br and O-H...
متن کاملPotassium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(-)·1.5H(2)O, the K(+) ion is hepta-coordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-bromo-2-chloro-benzene-sulfonamidate anions. The S-N distance of 1.582 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter-molecular O-H⋯Br and O-H⋯N hydrogen bonds. The asymm...
متن کاملPotassium N-bromo-2-nitrobenzenesulfonamidate monohydrate
In the title compound, K(+)·C(6)H(4)BrN(2)O(4)S(-)·H(2)O, the K(+) ion is hepta-coordinated by two O atoms from two different water mol-ecules, three sulfonyl O atoms from three N-bromo-2-nitro-benzene-sulfonamidate anions and two nitro O atoms from two N-bromo-2-nitro-benzene-sulfonamidate anions. The S-N distance of 1.576 (4) Å is consistent with an S=N double bond. The crystal structure is s...
متن کاملNovel synthesis of Pyrimido[4,5- e] [1,3,4] thiadiazines
Treatment of 1-(5-bromo-2-chloro-6-methylpyrimidin-4-yl)-1-methylhydrazine with dimethylthiocarbamoylchloride gave 7-chloro-N,N,1,5-tetramethyl-1H-pyrimido[4,5-e][1,3,4]thiadiazin-3-amine in basic acetonitrile. The latter compounds were reacted with secondary amines in boiling ethanol to afford the related 7-amino derivatives.
متن کاملNovel synthesis of Pyrimido[4,5- e] [1,3,4] thiadiazines
Treatment of 1-(5-bromo-2-chloro-6-methylpyrimidin-4-yl)-1-methylhydrazine with dimethylthiocarbamoylchloride gave 7-chloro-N,N,1,5-tetramethyl-1H-pyrimido[4,5-e][1,3,4]thiadiazin-3-amine in basic acetonitrile. The latter compounds were reacted with secondary amines in boiling ethanol to afford the related 7-amino derivatives.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013